rng('default') a = gevrnd(0,107,399,100,1);
Next we need to fit the parameters of the distribution:
Mdl = fitdist(a,'GeneralizedExtremeValue'); % Returns a PD object (Requires MATLAB later than 2009)
You can then calculate the ECDF: [f,x] = ecdf(a); % plot(x,f)
Then calculate the CDF implied by the fitted parameters:
y = cdf(Mdl,x); hold on plot(x,y) hold off
If you indeed wanted to look at a probability plot, you should know that by default probplot compares the data with a normal distribution. To change this, pass in the name of the distribution:
figure probplot('extreme value',a)
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